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Ducks need extra niacin (Vitamin B3) for their legs/feet when they are growing, but once they are adults they seem to do fine on layer feed. Probably start the ducklings on a game bird feed or niacin supplement.

As long as you have enough space I think it's fine. I have Muscovys (5) and chickens (12) together in a coop (10'x10'). The Muscovys mostly stay on the ground while the chickens stay up in the roosts. The ducks will peck at chickens if they get too close, but they don't follow and harrass...