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Yes, garlic is toxic to chickens and can cause chemical burns if not diluted (chew a clove of garlic in your mouth, the burning sensation is what I'm referring to) a small clove in a gallon of water wasn't strong enough to hurt her but also likely didn't help either. You offered supportive care...

Hi there, I'm happy to hear that your chick is better. Can you describe the symptoms, your brooder set up, heat etc? There are many reason chicks have a hard time breathing. You're very lucky your chick didn't die from the toxicity or get a burned crop/esophagus from the garlic.