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Either syrup of ipecac or a few tablespoon fulls of hydrogen peroxide will make a dog barf. We tend to keep both, some dogs are harder to make swallow than others and you use less ipecac. We also keep liquid charcoal like the vet has for situations where we don't know what or when a dog...

Hope you can get him to toss up whatever it is, did they tell you how? If it's already passed his stomach he's gonna need to be seen. Good luck.