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Too much corn and grain are the very reasons people end up feeding baking soda to goats all the time. The two above ingredients are fed to goats in quantity, in order to enhance milk production and really serve no other real world purpose.
This is the same as the cow dairy business. Remove bulk graining from the diet and the cow lives longer, produces for more years, but does not produce the daily quantity of milk. Interesting thing to note for any with dairy animals, is the more grain you feed the higher your risk of E.coli and mastitis. Coliforme counts drop by 75% on average when a grain fed dairy animal is pastured.
Just a few things to consider when setting up a feeding regime.
Do not feed a lot of alfalfa! They live it but it can kill your goats. I just bought a bunch go gates from Colorado nd had them delivered. The man I got yhem from had a lot of alfalfa hay in the trailer for them to eat on the 22 hr trip from Colorado to Texas. I had 5 of them die on me within the first few days. Their rumen shut down and the vet said too much alfalfa y coud kill them. She instructed me to give them only costal hay and that is what they have been eating and everyone is doing well.they shous have a salt block and a mineral block at all times plus baking soda available at all times. I now give them a small amt of alfalfa hay with the costal hay. They get some of their pellets when I milk them!
There is a reason we have "high frutose corn syrup" in this nation. Corn converts to sugar at a very high (glycemic) level in the digestive tract. That's why it is so "high energy". It is a very cheap, high calorie food.
In ruminants too much sugar makes them more prone to bloat. That is why other feed grains are better. The goats love corn because of that sugar conversion. But it does make them more prone to bloat. And that high glycemic (sugar) load is why people call it junk--like we call cereal junk food for human kids. Corn isn't the best choice, but it is the highest glycemic grain available. And goats LOVE it.
I just lost a goat to bloat a few weeks ago. And it was because of too much alfalfa and corn. I knew better, but goats love sweet things just like human kids love them. She was vaccinated against overeating, but she still bloated. I should have been more careful, but I just liked giving her treats.
I try to feed exclusively grass hay now rather than alfalfa, and a lower glycemic grain or goat food. I even feed them alfalfa (rabbit) pellets with a little goat feed to cut down a bit on the grain.
If your goat bloats (not just colic, but true bloat) from too much sugar (high glycemic grain diet), it is almost impossible to overcome. Colic is easier to deal with, but true bloat usually kills them. All the baking soda in the world doesn't fix a true bloat where the goat is down. It's just too late then.