How is your duckling doing now?
A lot of times ducklings will get food, grass, bedding or other debris lodged in their throat/nares. Usually it will resolve itself. Having water deep enough for them to dunk their head in would be a good idea.
How long has it been like this?
Distortions of the neck can be the result of many different problems. Nutritional, viral, bacterial, injury and genetics. Oftentimes providing supportive care, which could include vitamin supplementation (vitamin E, and thiamine specially), hand feeding, braces...
Bathing in water is a ducks main defense towards mites and lice, so if he's not getting in regularly you're probably going to have to set him in the pool a couple times each week so he can clean himself off.
Dawn dish soap will clean the feathers, but it is going to strip the natural water...
Very likely you would be seeing some form of eye irritation by now if there was damage done to the eye after being sprayed. Since you are not noticing any, I think it would be safe to say he is alright.
In my experience, if they are acting normally, the coughing may simply be due to inhaling irritants into their airways. Things that often cause this would be dusty feed, bedding, and mold in their living quarters. This will usually go away on its own considering the cause is addressed. Some of...
Not all egg/laying issues are a direct result of imbalanced calcium levels. New layers often experience difficulty passing their first few eggs. Feeding a feed designed for ducks along with oyster shells, and allowing birds access outside to absorb sunlight will help ensure adequate Calcium and...