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Supervise them when you put him in, and make sure the chicks have somewhere to hide if needed, a roost would be good since ducklings can't roost. I'd still get him a buddy

Ducks tend to pick on chickens, and they're much much bigger (even if the duckling is the same size now, he will soon outgrow the chicks). You can put them all together once they're mature. If the duckling is male, and he doesn't have any female ducks he will probably try to mate with your hens...