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Most small neighborhood type feed stores will be happy to open a bag and sell you 5# or so. I don't know if you can get TSC or Southern States or whoever to do that though.

I don't suppose that it could hurt - in very small amounts... And I'm SURE that your goats will love it! I bought a #50 bag of alfalfa cubes for my horse and she acted like I was trying to poison her... So I tossed a few the the chickens.. they totally ignored the weird, square, green rocks...