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Do you supplement niacin? Mixing the duckling feed with the chick feed is going to reduce the niacin percentage a little. If she's getting a lot of treats, that's also going to water down the nutrients from the feed a bit

She's still young. Is she preening herself when she gets out of the water? Does her oil gland looking okay? Ducklings shouldn't be unsupervised in water until 8 weeks. It definitely isn't safe for her to be out free ranging on a river. Predators, drowning, it's all a possibility.