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I don't know about a sure thing but I put powdered sulfer around my duck pen. I've never seen the snake that has been getting my ducks and it has been one a week so I don't really know if it is keeping it away or not. Make sure your fencing is small enough that the snakes can't get in anywhere...

I know this is a chicken forum but I've had a snake kill two of my ducks in the past two weeks. They are obviously way too big for him to get down but it hasn't stopped him. Anyone know of any other natural snake repellents? This is happening while I'm at work so there's been no intervening possible