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We recommend for novice duck keepers to give them the complex over treats, to reduce the risk of aspiration if given orally with a syringe. Duck seems to enjoy mealworms, peas, lettuce, tomatoes the most, it can also be mixed into a wet soupy feed. The reason we recommend not giving it in water...

You'll give each duck 1ml daily, over treats, or orally. For more info, please read the link in my signature.

Does it say they have this in stock where you're at? https://www.tractorsupply.com/tsc/product/durvet-hi-level-vitamin-b-complex

Do you live near a feed store like Tractor Supply?

The capsules are "flush-free" and thus won't work since they don't stay in the system long enough to be properly absorbed, you need plain niacin pills.

Could you share the brand, and how much water have you been putting it in with?

Have you read this? https://www.backyardchickens.com/threads/niacin-deficiency-in-waterfowl.1367557/