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If you'd used pasteurized ACV, the acidity may help to deter organism growth.....but some organisms can thrive in an acidic environment. But he unpasteurized ACV already has live organisms in it....which is the whole point of it. The acidity can be corrosive to the metal parts of the nipples...

If you used unpasturized ACV then it is a 'mother'......you've provided the perfect environment for one to grow. Clean all components again....not sure about bleaching the heater, go light with bleach..and put plain water back in. No need for the ACV, or if you feel you must give it, give it...