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If it turns out the spray was something harmful if ingested, then activated charcoal can help, if it hasn't been to long. If it's something toxic if inhaled or absorbed through the skin then the charcoal would not be effective. In those cases then sometimes vet care can be the best option, if...

How long ago did they spray? Without knowing what the actual spray was made up of, it's hard to say. If you know the name of the company, you could call them and ask what the actual compounds they used were, explain that you have birds and are worried. Every molt is different, some years they...

Not sure what black spots you are seeing? There are some darker under feathers showing, so maybe she's being pecked and feathers pulled? Or I also see some small pin feathers on her head, so she's likely molting. That can sometimes make them feel bad. Check her all over to see if you find...