Not with 100% certainty, unless you want to spend WAY more than any normal person does.
Google "cat fence" or "cat run", you will find a variety of webpages about systems that amount to (as previous poster says) tall fence that turns inward at the top, sometimes in a floppy way. Both DIY versions and moderate-priced commercial versions and at least one eyepoppingly-priced-up commercial version.
HOWEVER PLEASE NOTE that none of them really claim to be 100% catproof, just 'keeps in most cats except the very most determined'. Also note that there is frequent mention of problems with stray cats or raccoons getting inside and then trapped there.
I think about doing this for my own cats. Maybe I will someday. Here, the problem is not so much escape (my cats are lazy) or entrapped raccoons (although I know it'd happen, I'd be willing to check every morning and deal with it); my problem is that with the wind and ice and snow we get, I do not think that anything affordable would hold up. But maybe someday I will play with it.
If you are not comfortable with non-100%-catproofness, consider a large fully-caged run. I built a kind of fun one for my cats, there are pics around here somewhere (I bet if you used Search you could find the threads with pics), there are also lots of inspirational pics available online via googling. Mine has towers and bridges and so forth, not just a big boring walk-in cage, and the cats LOVE it.
Good luck, have fun,
Pat