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Here my goats get grass hay for the most part. Pregnant or lactating does get alfalfa. Orchard grass doesn't have a balanced calcium:phosphorus ratio. It has more phosphorus than calcium. If you look at this PDF, it has the ratios of some common feeds. It is geared towards horses, yes, but...

I am so sorry for your loss. Sounds like you really tried to help your poor lad. It is the worst when not even a vet can save them, I had that happen to a lil doe once. With you remaining goat (a wether too, right?) definitely add some ammonium chloride, fruit fresh, or apple cider vinegar...

Urinary blockages are basically a veterinary emergency. Either bring him to the vet, or bring the vet to him if he or she does farm calls. Absolutely give him banamine if you have it, and if you don't, get a bottle from the vet. That is the #1 painkiller, it is basically ibuprofen for goats...