Yes, I have used this method in the past. It's just like watching them fall asleep, very peaceful. I've never actually measured how much vinegar and baking soda to use. Too much can't hurt anything because you want to make sure the chick goes totally uncouscious. The trick is to get a very small...
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I've never heard of the method of culling. How does it work?
Just put the chick in a tupperware container with some baking soda. Pour in the vinegar and seal it up quickly. The chick just falls asleep and never wakes up.
I don't actually use this method though, because it's too much...