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Ducklings will need 10mg of niacin a day. More if they are deficient. It will take not days but weeks for a duckling/duck to recover from niacin deficiency.

I want your little guy to make it. He can make it! Two main possibilities with a swollen leg/foot. It is often either a displaced tendon or due to some infection.

This link should help. https://www.backyardchickens.com/forums/emergencies-diseases-injuries-and-cures.10/