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How much niacin are they getting and how do you administer it? She may need more, and at a dosage for an acute deficiency. If the others are eating the food before she can get to it and the niacin is in/on the food, she may not be getting enough.

Are you feeding a waterfowl-specific feed? If not, are you providing supplemental niacin to all your young ducks? If she's having trouble walking, it could be due to niacin deficiency. This is an informative thread that should help. Hope she's doing better soon.