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Are you giving chick grit? When you feed vegetables, grit helps to digest them better so you don't end up with constipated chicks. If there's a B-vitamin deficiency, regular strength vitamins may not be strong enough. B-complex would have the higher amounts so as to be therapeutic.

Is this chick smaller than the rest? Have you checked its legs for swelling or deformities? If nothing seems to be obviously wrong, perhaps it has a riboflavin deficiency. You can try giving it vitamin B-2 or get B-complex and give it to the chick each day for a few weeks and see if there's an...