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Because tomatoes belong to the nightshade family; all green parts are indeed poisonous... But my chickens don't eat them green and I think most avoid them because they inherently KNOW that ;).... they wait until RIGHT BEFORE I pick them, nice and red lol :P Edit to add* we cook them, removing...

If she's into canning, green tomatoes are excellent for increasing acidity to water bath canned food, like corn, so she doesn't have to pressure can because the acid in the green tomatoes would allow her to water bathe veggies like corn and beans just by adding a slice to each jar ;) That or...