Then I would just assume it's one of those weird things chickens do, and will probably not hurt them.
The chick starter "should" have enough calcium for them, but every now and then some individual chickens need a different amount than what is in the bag, or a feed company messes up the ingredients for a batch (that is really rare, but not quite impossible).
Sometimes chickens pick at things without actually eating them (maybe looking through to see if anything good is mixed in), and sometimes they actually eat it--either way, they are probably fine.