Give her 3 more weeks oflaying before you collect any eggs for hatching. the first eggs usually aren't fertile anyway. An egg does not immediately have veins inside. It can takeup to 3 days for veins to start showing and that's only if the hen has been brooding the egg(or it's been incubated) the whole 3 days.
If you want to check if they're fertilized,crack open an egg into a bowl and look on the yolk, kind of off to the side for a small, milky-ish, bullseye-looking spot. if it has that spot it's fertilized, that's the sperm. Do Not mistake the sperm for the white lumpy thing that keeps the yolk & albumen(egg white) attached, all eggs have that.
a hen won't sit on eggs consistiently until she decides she wants to go broody. usually when they go broody you will notice them stomping around the yard peeping or just being generally witchy. they usually(but not always) will pull some of their belly feathers out and make a nest with them.
I would just let the birds get used to all this new laying & breeding business. Readup on incubating duck eggs before you try it... it's never fun when you spend 28 days incubating eggs and no babies hatch.
ETA: you might consider rehoming one of your drakes(or trading for a hen) for the sake of the hen. it's always better to have more hens that drakes... when there's more boys the hens tend to get overbred.