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I agree Cmjusto- I dont think its the actual presence of the buck, although a smelly, hormonal buck 'could' leave an odor ON the doe that could possibly transfer to the udder and teats, then into the milk, but I doubt it. The does' own hormonal reaction to the presence of the buck 'could' be dumping hormones into her milk causing a funky taste- I've heard that alot. Although, the doe can go into heat without a buck around and cause the same issue with milk flavor, also a common occurance, I'm told.
I would also consider her feed, and any changes in her diet. Humans that eat alot of one food, ie; garlic, will have a garlicky smell and taste to their breastmilk, so I would imagine the same would apply to goats, but thats just my hypothesis...