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That's just the way I learned. I remember it being recommended in a book by Bob Gilsvik, "The Complete Book of Trapping", that somebody gave me when I was in jr high.
I've shot five or six skunks in 25 years and had just one spray. Looking around the web to see what the common knowledge is, I found some recommendations to shoot through the heart, some that said sever the spinal cord with a shot and then shoot through the head, and a few that said just shoot through the head... Although several did caution that shooting in the head would probably make them spray.
It seems people have pretty good success with the acetone and syringe, I remember that being recommended in Gilsvik's book also. One post I ran across on the web was from a fellow that worked in pest management. He figured he had dispatched 1500 skunks with a syringe and that he only had three of them spray.
As I said...you can read all you want in books.... sometimes the people who wrote them "thought" they knew what they were talking about . I know you're older than I am , but I've shot 3 x as many skunks as you have ( in the head ) with only 1 spray . Not saying your book isn't right , I just tend to go off of my record , and what has been passed down from my grandfather and other family generations of settling the "wild west " . For anyone who is interested, skinning out a deer and a skunk is basically the same , except the skunks skin is thinner . A rabbit now , that's like fine china .