Mosquito dunks are one option, another is a tablespoon or so of household bleach (chlorinated water). In many states putting any non-native species of fish in an outdoor tank of any kind is illegal with huge fines. While it's obviously a captive water source, there are many birds that will pluck a fish from a tank/pond and drop it in a nearby lake so I wouldn't suggest fish unless you've check with your state's fish & game department.