Air cell development is critical. It is the #1 reason, imo, for hatch failure in birds that have developed successfully up to lockdown.
That having been said, don't panic if one is different from the others. There is a range of "normal" and until you've hatched a lot of birds, you won't know what that range looks like. It does help a lot to look at the links provided and see photos of air cells. You've already been told the correct size at lockdown--1/3 the total volume. This will usually be near the large end of the egg, but it's possible for it to be on the side a bit or even in the wrong end (which can cause the baby problems, but doesn't necessarily mean it will fail--it's kind of like a breach birth at that point--unusual and difficult but not necessarily fatal). Mine usually develop at an angle in the large end. Babies can also successfully hatch with an air cell that is 1/4 or even nearly 1/2 the volume. Anything smaller than 1/4 will be dicey. Larger than 1/2 and you probably already have a dead bird in there.
Watching and recording air cell size will help you a lot with future hatches. Your humidity impacts how well the air cell develops, so if your air cells are too small, you'll know to lower your humidity next time, and vice versa. The porousness of the egg can affect air cell development too, and a large air cell may mean that the shell is more porous. Again, this doesn't spell doom, but it is a good reason to select eggs with good quality shells. An egg that dies during development, or never develops, will evaporate more quickly and result in an extra-large air cell--again, nothing you can do about that. It's best to remove them though, because the extra humidity created by the extra evaporation can cause the other eggs not to develop properly (learned that the hard way--but it's mostly a problem if you have a large batch and a bunch of eggs that aren't developing--for me it was quail eggs, which are so tiny I wasn't bothering to candle, which was a mistake).
An air cell that is too small does not provide enough space for the baby to get its bill in and breathe for the 12-48 hours between internal pip and external pip. An air cell that is too large does not provide enough room for the baby to complete its development. In any event, there is not much you can do at this point to help except just watch. Trying to help nearly always does more harm than good at this stage, especially if you're new at it.
That's a lot of information, and you don't need to remember it all at once. The main thing right now to take away is this: Pay attention to air cell size. Record it somewhere. Correlate it with your actual hatch rate. Over time, you'll learn what you need to know. In the mean time, relax and enjoy the hatch. Don't rush it. Just enjoy.
Good luck!!!!