That is not a calcium deficiency though more calcium shouldn't hurt, it could help. A hen is supposed to release one yolk a day to make an egg. And there are triggers for when she releases that yolk so the egg will be laid during daylight hours. Occasionally a hen may mess up and get that wrong. If it is a rare occurrence I just consider that an oops. We are all entitled to an occasional oops. It's when it becomes a regular thing that it becomes a problem.
If a hen releases two yolks at one time to start the internal egg making process you can get a double yolked egg. Some hens are more prone to that than others, but most of us have probably gotten a double yolked egg. They are not that unusual. If she releases two yolks in a day but they are separated a bit in time she can lay two eggs in one day. Since she may make a limited amount of shell material in a day the second one is often thin-shelled or soft-shelled. This sounds like what is happening to yours. Often does not mean always, but often when they do this they skip laying the next day.
There are certain triggers that tell the hen when to release a yolk to start the egg making process. If she is laying one egg a day, when she lays that egg triggers her releasing a yolk for the next day's egg. Of course they sometimes skip a day. Another trigger to release a yolk is light. It takes about 25 hours for most hens for an egg going from yolk release to an egg being laid. I'm sure there are other triggers but am not sure what they are but I'm confident nutrition may be one.
So what can you do? Calcium is not a root cause of this but feeding this hen extra calcium might firm up the eggshell a bit on that second egg. In things like this I try to determine if it is a flockwide problem or an individual hen problem. I don't want to mess up the flock by treating them when nothing is wrong with them.
Since light is one of the triggers how standard and consistent is the lighting? Are you supplementing lights? Do lights come on at different time at night, like a security light or even street light. Are they getting sufficient dark down time at night. Different hens can be affected differently by that, that's why only one may be affected.
How much protein are they getting? I'm going to go counter to the advice you see on here for practically any problem. I'm not suggesting you increase the protein. Quite differently, one of the things that I've read that can cause releasing extra yolks is that the protein content of their feed is too high. If you are feeding a high protein feed to them you might consider reducing the protein content a bit. See if that helps.
What I think is the root cause is that you have a defective hen. Her instincts just aren't quite right. You can try some of these things, they may help but it may be something you live with or you eliminate the hen from your flock.
I wish I had better news for you.