I don't think you should try putting ducklings in with a hormonal drake the ducklings won't make it. The ducklings need to be at least adult size and then females may have to be kept away until at least ready to lay so he won't mate with them too early. What breed is Nibbles?
The behavior your seeing is very normal especially with drakes so don't take it personal. But you can start training him to act nice .
Take the broom out with you when you go into Nibbles area when he starts for you put the broom between you and him don't let him come any closer if he tries hold him down by putting one hand at base of neck and the other where tail and back meet. hold him down on his belly till he quits fighting. You will be acting like a dominant drake to him. This all may sound hard but believe me it works my drake was a had full till I was told how to train him and it worked. For some reason having on different shoes gets them going too, I wore flip flops out the other night and my drake started biting my toes. A few shoves off and he was okay. So wearing the same shoes may help with the feet biting. When I wear my rubber boots I don't have this problem. Big thing is be persistent.
My Drake is exactly the same when I rescued him and adopted him into the house he was the sweetest thing and terrified of my two female Pekin and once I put him outside he like to rough house with a dog and the dog now lives elsewhere and he is the biggest spider in the bites like I think he thinks he's playing but now he's getting just aggressive flat out and if I wear anything that he can get to skin on my feet or my hands anywhere he attacks like horribly