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Did you give the injection under the skin or in the muscle? According to the vets at UC Davis injections for goats should be given under the skin. As for an oral painkiller, I know you can give aspiran to sheep so I can't imagine why you couldn't give aspirin to a goat.

If you are worried about calcium, alfalfa is not the answer. Alfalfa is high in calcium, low in phosphorous. Grass hays are high in phosphorous and low in calcium. I fed almost exclusively alfalfa to all my goats for years with never a problem. My guess, and it is only a guess, is your doe...