When I have ducks picking on each other, I separate them in a look—don’t touch” setup so that they can see and acclimate to one another without getting into a pattern of picking on each other or compromising the safety of any of them. I’m guessing there is a size difference between the pekins and muscovies, which may be a factor. As the ducks get older and closer in size, I would give them supervised time together for increasing periods of time, but would separate again if there was significant picking on behavior. I had to do this when introducing new ducks to my flock. It took a few days, but all of mine were full grown and about the same size.