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They can, sure, but the reason most people do not use medicated starter is because of the concentration of medication in the food. The ducks eat and process much more food in the beginning than chicks do, and the medicine in the medicated foods can actually poison them. Not to say it 100% will, and if your ducks are fine on it then that's your business, but it's better not to take the chance if you are new to ducks and only have a small number available to you.
Amprolium which is what is in medicated feed is a preventative....helps the chicks and duckling's guts build up a resistance to the coccidia protazoas that are in the soil. It's not an antibiotic which a lot of people seem to think it is. I've raised many ducklings on it over the years and have never had an issue using it. Back when I first started out with call ducks it was recommended to me to use it by one of the best call duck breeders around. You are right, it's everybody's business what they chose to feed, but the amprolium won't hurt them....and may in fact help them. Years ago the medication in the starter was medication that could hurt waterfowl and it's hard to convince people that the amprolium/amprol is not harmful.