There are about four ways (genetically speaking) to make a white chicken, and only one of them will work for making sexlinks.
To make sexlinks, you need the Silver gene (turns red/gold into white.) If you want to be sure of having that gene, you can use something like Delawares or Columbian Rocks or Columbian Wyandottes. The bits of black in all those patterns are enough to show that the white is actually caused by Silver. If your White Rocks are right for making sexlinks, they have that, plus a gene called Dominant White that turns black into white.
With those mixes:
If you get any chicks that are red/gold and grow white feathers in their wings and tails, then at least some of your White Rock hens are the right kind for making sexlinks. (Coloring would look very much like the commerically-available Red Sexlinks that get sold as ISA Brown, Red Star, Gold Comet, and so forth.) All such chicks would be pullets.
If you get any pullets that are all white without being pure White Rocks, then you have at least one White Rock with the wrong genes (probably a genetically black chicken, with Dominant White turning it to white: but being genetically black all over, it doesn't show the gold or silver that you need to see for sexing.) If you know which eggs came from which pen, and if you have them hatch inside mesh bags or baskets or something, you could watch for any white pullets from the pen that has no White Rock rooster. Or from either pen, a white pullet with a pea comb would have to be a mix (white from White Rock, pea comb from Dark Cornish.)
If you get any chicks that are all black, or black with white barring, then you also have at least one White Rock with wrong genes (probably a genetically black chicken, with or without white barring, that has the recessive white gene turning it white all over. Breeding to any other color means the chicks inherit only one recessive white gene, and since that is recessive it does not make the chicks white.)
Sometimes chickens that look white have more than one set of genes that make them that way, so there is a chance you might get different results from different ones of your White Rocks.
Any chick with a pea comb has at least one Dark Cornish parent.
Chicks with single combs have two single comb parents (White Rock, Rhode Island Red, or a mix of the two).