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The gas in question here is CO2 or argon, maybe nitrogen. None of these are dangerous unless you are breathing them, concentrated, with no oxygen. It's not that they are toxic, it's that they are taking the place of oxygen. So suffocation is the result. It's not like cyanide gas, or chlorine gas, or anything like that. It sounds worse than it is. The air we breathe contains oxygen, CO2, nitrogen, and argon. And a few other gases, as well. But in the correct proportions to sustain life.
I wouldn't be afraid to eat a bird killed with CO2 or argon, but it doesn't sound like it's quick or painless, as many of us no doubt hoped it would be.
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I've tried that, too. The first bird I killed by pithing, it worked perfectly. The next ones, it didn't. I've butchered a total of 9 now, (DH always did the deed for us before) and the last 2 were actually the worst. I just don't seem to be able to hit the correct area of the brain. I felt like I had tortured them to death, not at all what I intended.
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I'm about to either start chopping off heads, if I can figure out how to do it by myself, with only two hands. Or put them on a block or stump and shoot them point blank in the head. I'd be pointing down, so no worries about a bullet (or pellet) taking out anything else by accident.
I've tried hanging them upside down and cutting the throats. The skin of the neck is very loose, and if you don't have it pulled tautly enough, you don't get a nice, clean, deep cut, even if your knife is very sharp. Mine was sharp enough that didn't realize right away that I'd cut pretty deeply into the back of my thumb. The knife went into me just fine. The rooster, however, wasn't cut much at all, it took some sawing back and forth, both of us bleeding all over.
It wasn't pretty. I didn't like it one bit. I have yet to manage getting the head off with a knife in one nice meat stroke. Neither has my DH.
Twisting the neck, didn't work very well, my hands aren't strong enough to do it quickly and easily, like I've heard folks talk about.
When we raised turkeys, DH walked up behind them and shot them in the head, and they swayed a little and fell over. Then they flapped all over the place, he had to be quick to get ahold of them before the flapping started. One went all over the place, DH ended up having to retrieve it from under the pick up truck.
I wish you luck finding an acceptable method, when you do, please share it with me!
I truly hope I can manage it with a hatchet. An ax is too big, I can't handle it with one hand. (The other hand will be busy holding the chicken.)