Do his legs look okay??

Of course. Yes give them the B complex until you don't see any more shaky leg then wait a few days to a week before stopping if you get duck pellets after he gets over this he may not need anything since duck feed usually has the amount of niacin they need. But since he is already like this he needs help to get over it. It can get serious.
 
I know you have been putting them in the tub and they are getting exercise. He'll get over this with a little help. It's very common with ducklings that are fed chick starter and that is what most of us can get. I am going to be using Nutritional Yeast with my new duckling but I have the liquid b complex just in case.
 

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