Thanks for these details. Our formulated feed doesn't contain any alfalfa. I keep diluting the FF/alfalfa mix with more water and dry feed. The more I dilute it, the more they tear into their FF in the morning. I might try fermenting by itself and feed it separately, free choice.
I know your post was from several days ago and sounds like you were able to rectify it. Unpasteurized ACV will convert alcohol into more acetic acid. I have made ACV from scratch a few times now and my experience is the ACV mother is tempermental. The active/live mother will sit on top of the fermenting apple cider...if you move the jar, the floating mother will "die", sink to the bottom and in a week or two a new one will start to form. It takes 2-3 months to go from fresh pressed apple cider to apple cider vinegar. My point being is even in an ideal setting for ACV mother to do it's job, it takes quite a while for it to convert alcohol to vinegar. A few days is not going to do it, especially with all that stirring. ANY VINEGAR (white, rice wine, pasteurized ACV, unpasteurized ACV, etc) will help give a new batch of FF a headstart on acidity. The acid environment (which the lactic acid bacteria will eventually create in a few days) is important for the battle of the bacteria...will it swing to the putrefying bacteria or the fermentive ones? In most/many cases, the fermenting bacteria (yeasts and LABs) will just naturally win if you block most of the oxygen (very wet feed in a bucket fits the bill). Adding a SMALL amount of vinegar to a brand-new batch will hedge your bets, if you like, but it's not necessary.
In terms of your alcoholic smelling FF, personally, I would have composted it. Now that you mixed it with some other ingredients and the alcohol smell is gone, perhaps the alcohol was converted after all or simply just diluted to a point you can't smell it. I've read that chickens' livers are not well equipped to deal with alcohol, but surely they have encountered fermenting fruit in the wild and could tolerate it occasionally.
BTW, I am one of those note of the popular vote here on this thread in using starters. I do use a starter. I want to complicate matters for my own very good reasons. You certainly don't need them and I do recommend trying to make FF at least once without anything...just water and feed, so you have experience that it can and does work so simply. I'm not here to argue with anyone about the use of starters or even discuss it any further on this thread as that's not why this thread was started. PM me if your interested in how/why what do to my FF.
Like I said above, ACV after only a few days will not turn large amounts of alcohol into vinegar and it certainly won't turn it into alcohol. Sounds like you had some sort of yeast imbalance. It could have been from the probiotic supplement, but I doubt it. Your feed (and your local air) could just naturally be rich in yeasts ready to make alcohol. It's hard to tell. Start a (small) new batch with just water and feed and see what you get.
That looks like harmless Kahm yeast. Sometimes it stays thin like that and other times it gets thick and ripple-like. I get it all the time especially on my lacto-fermented pickles. No need to remove it, but you can simply stir it in if you wish. Some people get it more often than others and with different ferments. For example, our sauerkraut never grows Kahm yeast but our pickles do. I usually remove it in the pickles because it can change the flavor slightly. It's not required for lacto-fermentation, but I've never seen it anywhere but in a mature lacto-fermented product.
I hypothesize both yes and no. As with most "clinical studies" the amount of starter I used was WAY overboard! The bacteria that was awesome ran out of food too quickly, started to die off and when it was consumed, it was consumed by the yeast and allowed the yeast to take over.
Also, perhaps when the vinegar was added, it made the environment impossible for the bacteria to live,feeding the yeast more,causing a LOT of waste product alcohols. When I added the additional oatmeal, I'm bnot sure how it helped,but shortly after,it started smelling sweet again. Also, I was using the oatmeal consistency (how scientific?) in this thread.
Its great to sprinkle around my yard to give bonus surprises in the yard for the animals. The dogs love the stuff.