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That's just the way I learned. I remember it being recommended in a book by Bob Gilsvik, "The Complete Book of Trapping", that somebody gave me when I was in jr high.
I've shot five or six skunks in 25 years and had just one spray. Looking around the web to see what the common knowledge is, I found some recommendations to shoot through the heart, some that said sever the spinal cord with a shot and then shoot through the head, and a few that said just shoot through the head... Although several did caution that shooting in the head would probably make them spray.
It seems people have pretty good success with the acetone and syringe, I remember that being recommended in Gilsvik's book also. One post I ran across on the web was from a fellow that worked in pest management. He figured he had dispatched 1500 skunks with a syringe and that he only had three of them spray.
Not to sound rude...but you can read all of the books you want and never know how something is done until you do it over and over again . As it was mentioned ....where there is one skunk , expect at least 5 more . So , living in the country , like I have , you tend to shoot 1 one day...and find another in it's place a couple of days later . A shot to the head is the only way I recommend , unless you want to get sprayed .