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In the SKIN?!?! Do you know how bad that has to hurt?! If your vet isn't comfortable hitting a vein they could at least do an intra-cardiac stick to put them out of their misery! The whole point is that it's suppose to be fast...you'd be better off wringing their necks than injecting pentobarbitol in the skin.
And being jabbed in the heart would feel better? what...huh?
You can get the powder to stop bleeding clip the beak since it is the tip, tip it in the power to stop the bleeding, give her soft stuff in a deep dish until the soreness goes away.
I had to trim a overbite/crossbeak on a chick and it worked fine. I am braver I used a dremel tool and it was over in a second.
for future reference:
As far as putting her down, if that becomes necessary a stump and sharp axe is quickest if you cannot do this,. You or your stupid vet can put her down by simply giving her too much anestethia. I used it from my vet on a cotton ball in a baby food jar for a rat with cancer. She went to sleep, I left her lying with her nose in the jar about 10 more minutes and she was gone. with a chicken use a bucket, put the liquid on a rag in there and close the lid, she will drift off to sleep and just leave her there for 15 minutes - half an hour, it should do the trick and it is painless. They just get sleepy and get too much and go in their sleep.
I am glad she is doing better.