There have been a ton of threads here addressing such things. I'd do a search and read all the pros and cons of each.
Whatever your choice ( should the need arise) make it swift. PLEASE do not try one of the "suffocation" methods that have been discussed. I've read more horror stories that chicks are still alive after hours. I can't imagine the suffering they have gone through, just to put US at peace, and not have to do the deed ourselves.
There are lots of discussions about using vinegar and baking soda in a closed container, or putting a chick in the freezer to "put it to sleep". I just ask you-- do you want to suffocate or freeze to death. I can't imagine the pain. These are my opinions, and I'm sure you'll get others saying " it worked for me". I'm sure it may have, but I'm one who won't risk the suffering.
Small chicks ( day olds, etc) are small enough to use a sharp pair of scissors or shears ( very sharp). You can snip off their head, and it's over quickly. Hand held pruning shears, new or just sharpened, are VERY sharp and do a very quick job. ( I actually cut my finger with a pair of Fiskars pruners yesterday.... very bad cut, very deep, very fast- had it been a different angle, my finger would no longer be attached) If you can't watch, a sock or small bag over their head will help you ( don't try to cut through it though, only use what you must to not have to look). Others will pull their heads off ( yes, gruesome, but also quick if done without hesitation)
If you can't do it, you may have a friend or aquaintance who's willing to do it for you. Sometimes people without the attachment to the animal can be quicker. If you're going to do it, I suggest, getting everything you need to perform the task, and disposal ready, and just go do it. Don't think about it, just do it, and it'll be over quickly for the bird. If you have a breakdown later, that's fine ( not really for you, but for the bird), but get through the task first, so that you don't cause undue harm or suffering to the bird.
Small chicks are really too small for axes, or large implements. They're also too small to shoot ( we have shot some of our larger birds that required culling, at close range with buckshot or birdshot- very fast)
I wish you luck, it's a very hard, but necessary thing to have to do with our hobby.
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