It is a good use of egg shells and they are an excellent source of calcium.
However, egg shells are 95% calcium carbonate (CaCO3), not calcium (Ca). Oyster shells, other sea shells and coral contain equal levels.
During digestion, calcium carbonate is broken down into it's basic elements of calcium, carbon and oxygen, then reformulated in the uterus.
Because of the large particle size of crushed oyster shell, it can be an important source of calcium because they are retained in the upper digestive tract longer and reach the calcium absorption sites in the small intestine at night when eggs are normally in the shell gland.
Any additional source of calcium offered, should be in a separate container so hens can pick it up when they feel the need. They may not desire it when one offers it by hand. Plus, my hens would never let me close enough to take anything out of my hand.