The first bird, Millie, will not eat much from her dry food, both the 20% feed and scratch grains/worms, and even with hand feeding, she's more focused on the hands than the food.
I would completely stop the scratch grains.
Scratch grains are low in protein. If you think she might need more protein, you really want to avoid anything low-protein.
I would try a dish of wet mash made with the 20% protein food: just put a bit in a dish, and add water. Most chickens like it better that way.
If the "worms" are mealworms, I would stop them for now too. They are quite high in fat, and are not nutritionally balanced. So for a chicken that might have a nutritional imbalance, leave them out and see if anything changes.
Seriously, she's been looking for vulnerable points in my skin and tried to twist some off every time we feed her. The second bird, Pepper, has only just begun this behavior, and she's still extremely food motivated.
That is definitely odd, and I don't know what might be going on here.
As a practical matter, I would completely stop any hand-feeding. Depending on how bad it is, I might consider re-filling feed and water dishes while wearing gloves, or doing it during the night. (I have no tolerance for being hurt by my pets, but I am sometimes willing to change things a bit and see if that changes their habits.)
I would have suggested a change in food (in case there was a problem with one bag of food), but you have already tried that.
We're going to start giving electrolytes in their water just to be absolutely sure it isn't a nutritional deficiency
If you put electrolytes in the water, make sure they also have a source of plain water.
They should not need electrolytes if they are eating a complete chicken food and drinking plain water-- the same things that are in any electrolyte mixture are also found in their food.
But letting them have a choice (plain water AND water with electrolytes) should be safe enough, because chickens are usually pretty good at choosing the better option in cases like that ("better" being the thing that more closely meets their own personal needs.)
but can anyone recommend some good pinless peepers to use on juvenile birds? Is this really the last resort before having to cull?
Unfortunately, I don't know the answer to those questions.
This baby bird, a cream legbar, was different from the others from the get-go. She was far more bold than the other babies, accepting treats from our hands within two days of coming home. Whether in the cage or in the larger enclosure, she didn't care about being with her flockmates. She still doesn't. The only interaction she really initiates with the other birds is pecking at their tails...
Are you sure "she" is really a female? Some of those traits seem more common in male chicks (especially boldness and accepting treats from a human hand.)
It is unusual for a male or a female to pick at tail feathers that much, and it is a problem either way, but if the gender is wrong it may make a difference in how you deal with the matter. (For example, you might be more inclined to kill a male or try peepers on a female.)