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I metered his back, added 1 stop and that was that
I just start by thinking what I want out of the shot. I selected a pretty fast shutter speed (1/1000th) so that I could get a crisp handheld image, and there was plenty of light for that fast of a speed at ISO400. I then just moved the aperature up until my meter showed me 1 stop over exposure to compensate for the bright white...and click

I could have used a much lower ISO, slower shutter speed and wider aperature to get a bit more color but for a grab shot this will do.
The hash marks in the view finder have a center mark and then smaller and larger marks to each side that denote 1/3..1/4 and half stops (depending on your camera) Start by baselining the exposure on what ever you feel will give you the result youre after...again, keeping in mind to expose towards the brightest part of the scene, take a shot and adjust to suit what youre aiming to capture.
I remember when I started out, we were told to pick a shutter speed and worry with just the aperature to set our manual exposures. Then after awhile you start picking up on doing it without a great deal of initial thought, and then can use both settings to actual "make" a photograph instead of merely taking a picture. Ofcourse back then, we had to wait a few days for the film to be developed...now its instant education when you look at the LCD. Exposure is the base...composition and creativity come down the road IMO. Learn the basics and then you can tackle just about anything.
My favorite line about photography...."Learn all the rules, then break them!". I know photogs that still cant take a solid image but rely soley on impressive design and edit work to create stunning images.....welcome to digital manipulation! Im to old to learn all that junk so I do everything in my power to get it as close to right in camera.
My nemisis is landscapes. Eventually I will get to a point where I feel like I am getting somewhere LOL! Funny part is, my highest grossing image came from a wide angle haha! Go figure LOL!