Yes, eventually, the water buckets have a life span. How to clean it, rinse it out with the hose while filling it. The rust is just iron oxide, an essential mineral in a chicken's diet.
Well, it would be, most forms of iron oxide isn't water soluble or bio available. With iron the source matters, with the majority of iron coming into organisms from meat as the heme type iron bound in fish, chicken, red meat is very bio available while nonheme type iron coming from vegetables or grain has a very low absorption rate. 10% to 2% versus up to 30% from organ meat.
So the reason that sludge builds up in rusty water buckets is because the iron oxides, red, black, or yellow, are all non soluble in water. If the chickens or ducks ingested the oxides it would pass through harmlessly.
Your chickens are more likely to suffer from iron deficiency than being "poisoned".
Remember, the dose is the poison. Tiny amounts do no harm and might well do some good. Bio availability is as important as the amount or the element.
Well, it would be, most forms of iron oxide isn't water soluble or bio available. With iron the source matters, with the majority of iron coming into organisms from meat as the heme type iron bound in fish, chicken, red meat is very bio available while nonheme type iron coming from vegetables or grain has a very low absorption rate. 10% to 2% versus up to 30% from organ meat.
So the reason that sludge builds up in rusty water buckets is because the iron oxides, red, black, or yellow, are all non soluble in water. If the chickens or ducks ingested the oxides it would pass through harmlessly.
Your chickens are more likely to suffer from iron deficiency than being "poisoned".
Remember, the dose is the poison. Tiny amounts do no harm and might well do some good. Bio availability is as important as the amount or the element.
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