Ant's usually travel in line's back and forth to where the nest or hill is at. Couldn't you follow them (standing off to the side) to see where it is located at?
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ThanksI use Orthene when I can find the mound. Takes about a tablespoon per mound. I sprinkle it on the mound then just lightly disturb it so a few ants come out. They then take into the mound and it dies. Takes about 24 hours. Instructions say water it in but I seldom do that.