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with ours, we didnt' have people agression with people we introduced (but I can't say how it'd be with strangers out-of-place). I'm pretty comfortable projecting alfa dog naturally and my 100 lb pups got it and never questioned it or challenged it. they get pack structure, so it wasn't something I had to work at on a daily basis. however because they are bred for killing hogs they are fighters and the problem we saw was that should they get in it with another dog, they do NOT stand down. the second fight we had between the two pups was 140 stitches to close the wounds up on the pair of them. I've had to separate them three times, and you cannot talk them, yell them, or half-drown them out of a fight - once they're in, they're in all the way. it's what they're bred for.
my worry wouldn't be that they'd not respect your alfa-ness - if you're clear about it they will get it and it shouldn't be a lot of effort to maintain - but that should they get in it with your other dogs (and they want to know pack status) that they can do real harm and it'll take two people to separate the dogs. and that, by the way, is where you get hurt.
FWIW, we've found the safest way to separate fighting dogs is with 2 peiople - each person graps one dog's hind legs. then IF you can separate them, you can keep them separate by "wheelbarrowing" them away from each other and you can stay out of bite range as long as you keep the hind legs gripped.
I will say that once separated, neither of our boys offered or attempted to bite us, even when puting a chain on their collars to tie them to separate ends of the pen, but it took a good 10 minutes before they stopped tgrowling, barking and rying to get at each other and finish their fight.
the stupid thing is that after stitches, they spent the next week licking each other's wounds.
I loved these dogs but my hubby had real issues with their occasional agression with each other and in truth we didn't have a job for them, and they really needed a job.
most catahoulas aren't 100 lbs - the majority are 40-60 lbs, but if I had kids I might want to consider their hunting dog nature. lots of folks keep dogs with fighting/hunting in their breeding and have no issues with it, and have no problems between their kids and the dogs , but its something to think about.