I recommend against it, but its usually sold in 8' and sometimes 12' lengths, with a "wave" profile. You have to pre-drill holes for polycarbonate, larger than the screw, to allow for thermal expansion and contraction, and its wave profile means there are no flats, making it easy to place screws in a way not perpendicular to the material, adding to the potential for leaks and stress fractures. For that reason, the half hex profile, rather than the smooth wave, tends to be much more forgiving - probably worth the greater expense for that factor alone.Interesting. I'll have to check it out in store because the website doesn't always show what's available at price. But from the prices I did see... it looks like plywood would still be cheaper in my area. I can get a 4x8 for around $53 while the polycarbonate is $24 for a 26"x6' piece... I think.
and in my area, you are still looking at about $52-55 per 32 sq ft for the half hex profile. and you will need ribbing for it - a further (small) expense.