A while back I expressed my ignorance about "how" fermentation works to "enhance" the nutrition of grains. I believe it works, but all the "hows" have me stumped and a lot of the pro-fermentation information on the Internets is just ... vague. One of the vague claims of how fermentation boosts the nutritional value of grains is through the reduction of anti-nutrients. Here is the citation of a study that specifically addressed the question of the reduction of the phytate in Rye, Wheat & Oats via fermentation. The conclusion seems to be it is the lowering of pH through fermentation that allows the phytate reductation process inherent in the grains themselves to get to work ... "Lactic acid fermentation of cereal flours resulted in a 100 (rye), 95−100 (wheat), and 39−47% (oat) reduction in phytate content within 24 h. The extent of phytate degradation was shown to be independent from the lactic acid bacteria strain used for fermentation. However, phytate degradation during cereal dough fermentation was positively correlated with endogenous plant phytase activity (rye, 6750 mU g- 1 ; wheat, 2930 mU g- 1 ; and oat, 23 mU g- 1 ), and heat inactivation of the endogenous cereal phytases prior to lactic acid fermentation resulted in a complete loss of phytate degradation. Phytate degradation was restored after addition of a purified phytase to the liquid dough. Incubation of the cereal flours in buffered solutions resulted in a pH-dependent phytate degradation. The optimum of phytate degradation was shown to be around pH 5.5. Studies on phytase production of 50 lactic acid bacteria strains, previously isolated from sourdoughs, did not result in a significant production of intra- as well as extracellular phytase activity. Therefore, lactic acid bacteria do not participate directly in phytate degradation but provide favorable conditions for the endogenous cereal phytase activity by lowering the pH value." And for those of us tracking the "how long does proper fermentation take," the results above took 24 hours ... in dough. Dough has already been processed a bit, so if I person is fermenting whole grains their results will likely vary. Here is a link to the page with that citation and qualified access to the 2007 study:
http://pubs.acs.org/doi/abs/10.1021/jf063507n