Help! Quail membrane turned brown

One hatched. One zipping. This was the first pip. The chick rolled it around and I see membrane is brownish humidity at 65
 

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I got another one! It's been part way zipped since 8am it's just like it can't open the egg? It is peeping and pushing hard. Should I help it? I've looked at the article and am not sure.
 

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