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This attitude just strikes me as giving the entire class detention because one student shot a rubber band at the teacher's backside.
The idea might be to get the rest of the class to talk, but think about it, what happens to the student who talked?
In the world of the big stores, they will lose out on the bigger, nicer vendors who have plenty of other places to sell their wares, or the vendors will raise their prices which will get passed on to the consumer.
It's easy to find the information on vendors who won't allow their merchandise to be donated. You just ask and observe. It's really that easy.
Also, as I mentioned, the problem may not be the store, it may be the charities. Some charities won't take donations. Some charities won't pick-up and the store isn't able to organize deliveries (they may not even have trucks of their own). Some charities require items to be pre-sorted, and the store may not have the manpower to do that. Or the store may trash items but regularly donate large sums of money to various charities.
Some call it waste, but on the flip side, why is anyone entitled to the leftovers? If someone really wants to feed the homeless so much, they can volunteer to pay higher taxes to pay for welfare and heath care programs. I would hope that everyone involved in putting such pressure on the big companies is also making charitable donations of their own, either of goods or of time, rather than being those who expect to benefit from such donations.