If Layer feed is all they eat they should be getting enough calcium from that alone. Layer feed should have about 4% calcium where most other chicken feed has only 1%. They may pick up additional calcium from some plants or creepy crawlies they eat if they forage. If your soil has limestone as a native rock they can get some calcium from that. But if you feed them treats they may not be getting enough calcium. I think it is a good idea to offer a calcium supplement on the side, not mixed with their feed. If they need it they should eat it. If they don’t need it they probably won’t eat much.
Your egg shells can tell you how you are doing. If the egg shells are hard, what you are doing is working. If they are thin or soft, they probably need more calcium.
It gets more complicated, it always does. On rare occasions you can get a hen that just does not eat the calcium she needs even if it is available or, if she eats it, her body does not use it properly. There is just something wrong with that hen. In general, if you have a problem with most or every hen in your flock you have a flock problem and need to address the entire flock. If all the hens but one are fine, you have a hen problem and need to address the individual, not the flock.
It is fairly common for a pullet just starting to lay to lay some strange eggs. They may be soft-shelled, no shells, no whites, no yolks, double yolked, weird shapes, really strange. Her internal egg making factory has a lot of parts. A pullet just starting to lay may just need to work out some bugs. Give her a couple of weeks before you start to worry. As complicated as that internal egg making factory is the remarkable thing is that most get it right to start with.