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They'll stand guard, in fact, they'll will stand there and watch while the snake eats anything it wants.
Once they become accustomed to something then to them it's normal and they will be about as good for a guard as a blind man.
I've raised guineas off and on all my life since I was 12.
The last ones I had, I killed 4 snakes and then only reason I killed them was I happened to walk up on them while they were heading toward my coop.
Personally, if the snake is of any size they do not attack it. In fact, they are similar to chickens, if they can consume it, they'll go after it.
I really do not believe they deter snakes in any fashion. BUT..they are funny to watch and GREAT insect eaters and their eggs are tasty!
And..noisey is an UNderstatement. Just ask my city slicker wife lol
Enjoy them!