Thanks for the warning, not something I would have thought of. Though I am the one who cut & canned a half a bushel of jalapenos with no gloves on. I enjoyed the zing every time I licked my fingers for weeks. My eyes didn't enjoy it so much.I don't have enough freezer space so I can mine but a friend who does freeze hers says she does it whole with the skin on. She says the process breaks the flesh down into a purée and when she thaws them to use she grabs them by the stem end and the firm green sorta-stem part and the skin simply slip away.
You might want to try a few intact and see if you find it less tedious. I know one year when I was taking skins off before canning the acid got to my hands and they were just sore from handling all the skins.
